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Anglický jazyk
Garner's aldehyde
Autor: Moumita Ghosh
Chiral amino aldehydes are remarkable, as their aldehyde groups can be converted into a wide range of structural frameworks are the intermediates in several important industrial processes. However, the characteristic reactivity of amine and aldehyde functionalities... Viac o knihe
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O knihe
Chiral amino aldehydes are remarkable, as their aldehyde groups can be converted into a wide range of structural frameworks are the intermediates in several important industrial processes. However, the characteristic reactivity of amine and aldehyde functionalities is a major task in case of preparation and synthetic efficacy of a-amino aldehydes as nitrogen protection assists undesired epimerization processes. Fischer's discovery of glucosamine in 1902 in which unprotected amine and aldehyde functionalities are stabilized as a cyclic hemiacetal is the first example of unprotected a-amino aldehydes. Later on, he also synthesized glycinal, which was characterized through degradation studies due to its inherent instability via self-condensation. The probability for intramolecular stabilization of a-amino aldehydes is not significant but the presence of incompatible functional groups make these unstable and hence, suitable N-and C-protection is vital.
- Vydavateľstvo: LAP LAMBERT Academic Publishing
- Rok vydania: 2019
- Formát: Paperback
- Rozmer: 220 x 150 mm
- Jazyk: Anglický jazyk
- ISBN: 9786200275783
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